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Circulation Classification and Source Analysis of Summer Ozone Pollution in Chengdu
SHI Wenbin, QU Kun, YAN Yu, QIU Peipei, WANG Xuesong, DONG Huabin
Acta Scientiarum Naturalium Universitatis Pekinensis    2022, 58 (3): 565-574.   DOI: 10.13209/j.0479-8023.2022.016
Abstract537)   HTML    PDF(pc) (2726KB)(224)       Save
In order to explore the impact of large-scale circulations on O3 pollution in Chengdu, based on the 700 hPa geopotential height field in the Sichuan Basin (SCB) and using the T-PCA method, the atmospheric circulations in the summer of 2015–2019 (June–August) were classified into five circulation patterns, and the characteristics of O3 pollution and O3 sources in Chengdu under different circulation patterns were identified. Among the five types of circulation patterns, the northeast-high pressure (NEH) pattern and the under-high pressure field (UNF) pattern generally led to higher air temperature, and lower humidity and cloud cover in the SCB. Air temperature change compared to the previous days showed an obvious increasing trend in the SCB under the UNF pattern, kept stable under the NEH pattern, and indicated cooling effects with varying intensities under the other three circulation patterns (the southeast-high pressure pattern, the northwest-low pressure pattern and the northwest-high pressure pattern). The meteorological conditions under NEH and UNF were more conducive to the photochemical production of O3 in the SCB. During the study period, O3 concentrations and the percentages of over-standard days of O3 in Chengdu under NEH and UNF were significantly higher than those under the other three circulation patterns, and thus NEH and UNF were the main circulation patterns that were related to O3 pollution in summer. Months with more severe O3 pollution in Chengdu tended to have higher proportion of days under the NEH and UNF patterns. The simulation studies of O3 sources in Chengdu in summer suggested that O3 was mainly derived from the SCB (55.0%), with local contribution of Chengdu (31.6%), and other important contributing cities including Deyang (5.4%), Chongqing (4.0%), Ziyang (3.9%) and Meishan (2.2%). However, O3 sources in Chengdu under different circulation patterns showed different characteristics. Under the NEH pattern, O3 transport within the Chengdu Plain had notable impact on O3 pollution in Chengdu, with a significant increasing contribution from Deyang (14.9%). By contrast, under the UNF pattern, O3 pollution in Chengdu became more localized, with nearly half (46.8%) of O3 contributed by local emissions. 
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A Study of the Water-Soluble Inorganic Salts and Their Gaseous Precursors at Wangdu Site in the Summer Time
YE Nini, LU Keding, DONG Huabin, WU Yusheng, ZENG Limin, ZHANG Yuanhang
Acta Scientiarum Naturalium Universitatis Pekinensis    2016, 52 (6): 1109-1117.   DOI: 10.13209/j.0479-8023.2016.116
Abstract890)   HTML    PDF(pc) (2520KB)(726)       Save

The authors conducted on-line measurements of water soluble inorganic ions and their gas phase precursors for more than 30 days at Wangdu, Baoding City in summer in 2014 with a Gas and Aerosol Collector (GAC). It was found that, the observation site was always subjected with an ammonia rich conditions; the averaged PM2.5 concentration was 68.2 μg/m3, of which the detected SO42-, NO3-, Cl-, NH4+ and K+ by GAC was 12.6, 8.5, 1.4, 11.7 and 0.7 μg/m3, respectively, consisted 51% of the total mass of PM2.5. All these observed pollutants showed distinct diurnal variations: SO2, SO42-, NO3-, NH4+ and Cl- showed a morning maximum, HCl and HNO3 presented an afternoon peak, and NH3 possessed a day-night variations. As depicted by the analysis of Sulfur and Nitrogen Oxidation Rates (SOR, NOR), fast transformations of trace gases into secondary inorganic aerosols were indicated. The averaged value of SOR and NOR are 0.43 and 0.22, respectively. The variation of SOR and NOR inferred that both gas phase and aqueous oxidations contributed to the fast transformation that formed water soluble inorganic salts.

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An On-Line Method of Measuring Gaseous Ammonia and Ammonium in Aerosol in Atmosphere
DONG Huabin,ZENG Limin
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract741)            Save
An ammonium detection module was developed to measure the concentration of ammonia in gas phase and ammonium in aerosols. Connecting with gas & aerosol collector (GAC) system, the module could perform online measurements. This paper introduced the configuration and the running procedure of the module and showed the result of condition experiments. The module was applied to the observation of air quality in Guangzhou and compared with PILS system. The correlation coefficient(R) between the module and PILS was 0.820 7. If just night data was analyzed, the coefficient was 0.970 3. Possiblely the measurement was interfered by temperature. The NH4+concentration in PM2.5 which was measured by the module was 92% of that in PM10 which is measured by PILS. It illustrated that ammonium was mainly in fine particles.
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Measurement and Discussion of Carbonaceous PM2.5 during Winter in Beijing
HUAN Ning,ZENG Limin,SHAO Min,CUI Liang,MAO Jietai,ZHOU Nan,DONG Huabin,YU Zhongying,LUO Zhiming
Acta Scientiarum Naturalium Universitatis Pekinensis   
Abstract791)            Save
The carbon content in PM2.5 is measured by Aethalometer (for BC) and Sunset OC/EC analyzer (TOT, for EC), respectively, during the winter of 2004 in Beijing. The experimental result shows that black carbon and elemental carbon have a good agreement with a high correlation coefficient (R2=0.80), so does organic carbon and elemental carbon (R2=0.82). The ratio of OC to EC is higher in the daytime than at night and higher at normal day than at temperature inversion day. In addition, there is no significant difference of OC to EC ratio between day and night at temperature inversion day. The average ratio of OC to EC is 4.76. It is also proved that ratio of OC to EC larger than 2 is not the exact index for secondary pollution.
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